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HETEROCYCLIC COMPOUNDS, MEDICAMENTS CONTAINING SAID COMPOUNDS, USE THEREOF AND PROCESSES FOR THE PREPARATION THEREOF

The present invention relates to compounds of general formula (1) and the tautomers and the salts thereof; particularly the pharmaceutically acceptable salts thereof with inorganic or organic acids and bases; which have valuable pharmacological properties; particularly an inhibitory effect on epithelial sodium channels; the use thereof for the treatment of diseases; particularly diseases of the lungs and airways

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Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

 

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Structure-activity relationships of benzylidene anabaseines in nicotinic acetylcholine receptors of cockroach nerve cords

Ten analogues of 6?-chloro-3-benzylideneanabaseine (CBA) bearing substituents at the ortho- and the para-positions of the phenyl group were synthesized, together with two related compounds. The affinity of the synthesized compounds for nicotinic acetylcholine receptors (nAChRs) in the nerve cord of the American cockroach (Periplaneta americana L.) was examined by the radioligand binding assay using [3H]epibatidine (EPI), a nAChR agonist. All 12 tested compounds inhibited [3H]EPI binding, showing Ki values ranging from 14.6 to 6830 nM. The potency variation of para-substituted CBA analogues was explained by the steric (DeltaB1) and electronic (sigmap) parameters of the para-substituents, or by the steric parameter and the charge of the N1 nitrogen atom (qN1). Among the CBA analogues, only two compounds containing a dimethylamino group and a methoxy group at the para-position showed high insecticidal activity against the German cockroach (Blattella germanica) when injected after pretreatment with metabolic inhibitors. High-affinity analogues of CBA might be suitable probes for use in classifying and characterizing insect nAChR subtypes.

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Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

 

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Preparation of 6-hydroxy-3-pyridinecarboxylic acid esters

STR1 R, R1, R2 and R3 are alkyl. II and III are new and I is a known intermediate for insecticides.

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Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem