Category: 151-10-0

Zhang, Yuanyuan published the artcileChiral Selenide-Catalyzed, Highly Regio- and Enantioselective Intermolecular Thioarylation of Alkenes with Phenols, Application of 1,3-Dimethoxybenzene, the main research area is chiral phenol preparation regioselective enantioselective diastereoselective; alkene phenol thiosuccinimide three component thioarylation chiral selenide catalyst.

Enantioselective electrophilic three-component thioarylation of alkenes by chiral selenide catalysis with free phenols as arylating sources is disclosed. A variety of chiral phenols, e.g., I, were prepared in high regio-, enantio-, and diastereoselectivities. Mechanistic studies revealed that this transformation went through carbon nucleophilic attack to give the products rather than the process of intramol. rearrangement of phenolic ether intermediates. The application of this organocatalytic method in the alkylation of methoxy-substituted benzenes elucidated its generality.

ACS Catalysis published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Application of 1,3-Dimethoxybenzene.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Zhu, Deng published the artcileN-Selenocyanato-Dibenzenesulfonimide: A New Electrophilic Selenocyanation Reagent, Category: isoquinoline, the main research area is selenocyanato dibenzenesulfonimide preparation selenocyanation nucleophile; tandem selenocyanation cyclization alkene phenol selenocyanato dibenzenesulfonimide reagent.

A new electrophilic selenocyanation reagent, N-selenocyanato-dibenzenesulfonimide, was readily prepared in two steps from com. available dibenzenesulfonimide for the first time. A variety of electrophilic selenocyanation reactions of nucleophiles have been achieved using this reagent as the selenocyanato source under mild and simple conditions. Numerous SeCN-containing compounds were obtained in moderate to excellent yields. Meanwhile, a Lewis acid-mediated tandem selenocyanation/cyclization reaction of alkenes with phenols, which provided simple methods for the formation of various SeCN-containing chromanes and dihydrobenzofurans in moderate to good yields, has also been developed.

Synthesis published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Category: isoquinoline.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Sun, Li published the artcileElectrochemical Radical Selenylation of Alkenes and Arenes via Se-Se Bond Activation, Computed Properties of 151-10-0, the main research area is selenoether preparation regioselective; alkene activated arene electrochem radical selenylation.

A novel electrochem. radical selenylation of alkenes and activated arenes without external oxidants is reported. The diselenide was fully transformed into Se-centered radicals through electrochem. Se-Se bond activation. Three-component radical carbonselenation was successfully realized using styrenes to trap the RSe radical. Besides, the direct coupling of RSe radicals with activated arenes was further developed. Using this atom-economic protocol, diversity of unsym. aryl-aryl, aryl-alkyl, and alkyl-alkyl selenoethers was obtained regioselectively, which has potential application in biol. chem.

Organic Letters published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Computed Properties of 151-10-0.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Zhang, Yingmu published the artcileA mesoporous NNN-pincer-based metal-organic framework scaffold for the preparation of noble-metal-free catalysts, Product Details of C8H10O2, the main research area is zirconium terpyridinephenylcarboxylate MOF preparation gas adsorption isotherm epoxidation catalyst; borylation catalyst zirconium terpyridinephenylcarboxylate MOF; surface area pore size distribution thermal stability zirconium terpyridinephenylcarboxylate.

Through topol.-guided synthesis, a Zr-based mesoporous MOF was successfully constructed, adopting a β-cristobalite-type structure. The MOF is embedded with well-arranged terpyridine coordination sites for facile post-synthetic metalation, and can be effectively used as a general scaffold for the preparation of noble-metal-free catalysts. For instance, the scaffolded metal@MOF material exhibits highly efficient catalytic activity for alkene epoxidation and arene borylation.

Chemical Communications (Cambridge, United Kingdom) published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Product Details of C8H10O2.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Ye, Ai-Hui published the artcileTMSCl-Catalyzed Electrophilic Thiocyano Oxyfunctionalization of Alkenes Using N-Thiocyano-dibenzenesulfonimide, Recommanded Product: 1,3-Dimethoxybenzene, the main research area is chlorotrimethylsilane catalyzed electrophilic thiocyano oxyfunctionalization alkene; nitrogen thiocyano dibenzenesulfonimide electrophilic thiocyanation reagent.

Numerous electrophilic thiocyano oxyfunctionalization reactions of alkenes have been achieved using N-thiocyano-dibenzenesulfonimide, which is a new electrophilic thiocyanation reagent and could be easily prepared in two steps from dibenzenesulfonimide. This approach provides efficient, simple, and modular methods for the formation of SCN-containing heterocycles such as lactones, tetrahydrofurans, dihydrofurans, and dihydrobenzofurans in moderate to excellent yields. Meanwhile, diverse oxa-quaternary centers were rapidly constructed. Addnl., this protocol is free of transition metals and features broad substrate tolerance and mild reaction conditions.

Organic Letters published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Recommanded Product: 1,3-Dimethoxybenzene.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Kim, Yerin published the artcileEfficient Synthesis of Diarylmethylamines via Lewis Acid Catalyzed Friedel-Crafts Reactions of Donor-Acceptor Aziridines with N, N-Dialkylanilines, Category: isoquinoline, the main research area is diarylmethylamine scaffold preparation chemoselective; aziridine dialkylaniline Friedel Crafts Lewis acid catalyst.

A method for efficient and mild synthesis of diarylmethylamine scaffolds I [R1 = Ph, 1-naphthyl, 4-ClC6H4, etc.; R2 = Me, Et, Bn, etc.; R3 = 4-NMe2C6H4, 2-Me-4-NMe2C6H3, 1-pyrrolidyl, etc.] via Lewis acid catalyzed Friedel-Crafts reaction of donor-acceptor aziridines with N, N-dialkylanilines in high yields (up to 88%) was reported. This reaction was suitable for the synthesis of various compounds I and had a broad scope for electron-rich arenes, including dimethoxybenzene.

Synthesis published new progress about Anilines Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Category: isoquinoline.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Bhatthula, Bharath Kumar Goud published the artcileA simple method for the synthesis of sulfonic esters, Application of 1,3-Dimethoxybenzene, the main research area is aryl heteroaryl sulfonic ester preparation solvent catalyst free; arene heteroarene dialkyl sulfate alkoxysulfonylation.

An efficient and simple approach for the direct synthesis of aryl and heteroaryl sulfonic esters was developed using DMS and DES as alkoxysulfonylation reagents. The reaction is operationally simple and scalable. This protocol does not require solvent, expensive catalysts, base, ligand additives or other reagents. A wide range of sulfonic esters were synthesized in moderate to good chem. yields. This method has the advantage of low cost, facile and tolerated a wide range of substrates.

Synthetic Communications published new progress about Anilines Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Application of 1,3-Dimethoxybenzene.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Nguyen, Hai Truong published the artcileImidazolium Triflate Ionic Liquid Improves the Activity of ZnCl2 in the Synthesis of Pyrroles and Ketones, Product Details of C8H10O2, the main research area is pyrrole preparation; aniline acetonylacetone Paal Knorr reaction imidazolium triflate zinc catalyst; ketone preparation; arene acetic anhydride Friedel Crafts imidazolium triflate zinc catalyst.

An efficient catalytic system, ZnCl2/([AMIm]OTf), for the synthesis of pyrroles I (R = Ph, 2-methylphenyl, 4-nitrophenyl, 3,5-dichlorophenyl, etc.) and ketones R1C(O)CH3 (R1 = 1H-indol-3-yl, 5-chloro-1H-indol-3-yl, 5-bromo-1H-indol-3-yl, etc.) was developed. The method provides desired products in good to excellent yields with high selectivity under mild conditions.

Organic Preparations and Procedures International published new progress about Anilines Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Product Details of C8H10O2.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Matsukawa, Yuta published the artcileReactions between 5-Nitroso-1,3-diphenyltetrazolium Salts and Electron-Rich Arenes, Amines, Thiophenol, Sulfoxides, and Thioanisole, Product Details of C8H10O2, the main research area is nitroso diphenyltetrazolium salt arene amine thiophenol sulfoxide thioanisole oxidation.

A series of reactions between 5-nitroso-1,3-diphenyltetrazolium tetrafluoroborate and methoxybenzenes such as 1,3,5-trimethoxybenzene, 1,3-dimethoxybenzene, methoxybenzene, amines such as aniline, N,N’-bianiline, benzhydrylamine, benzylamine, thiols (thioanisole, thiophenol), sulfoxides (DMSO, di-Ph sulfoxide) and di-Ph sulfide, most of which are generally accepted as being inert to nitroso groups, is reported here. The tetrazolium-activated nitroso functionality is capable of oxidizing the aforementioned substrates to give the corresponding oxidized products e.g., azobenzene, and the nitroso tetrazolium itself is transformed into the corresponding amide or hydroxyamide I [R = NH-, O-], depending on the nature of the reaction partners. In the case of thioanisole, an addition product II•BF4- was obtained.

Bulletin of the Chemical Society of Japan published new progress about Anisoles Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Product Details of C8H10O2.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Wang, Jing-Hao published the artcileThiol Activation toward Selective Thiolation of Aromatic C-H Bond, Name: 1,3-Dimethoxybenzene, the main research area is thiophenol aryl ether regioselective electrochem thiolation; diaryl thioether preparation.

An effective model for regioselective thiolation of the aromatic C-H bond by thiol activation instead of arene activation was disclosed. This method was applied into anisole derivatives that are not available in the arene activation approach to forge a single thioether isomer with high reactivity.

Organic Letters published new progress about Anisoles Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Name: 1,3-Dimethoxybenzene.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem