Tag: 755.0383

An approach to novel NIR dyes utilizing α-effect donor groups was written by Langhals, Heinz;Blanke, Patrick. And the article was included in Dyes and Pigments in 2003.Reference of 110590-84-6 This article mentions the following:

Light-fast and strongly fluorescent near-IR-absorbing dyes have been obtained by the core-substitution of perylene bisimides with joined nitrogen donor groups. Emission has been recorded beyond 1100 nm. Complete Gaussian analyses were successful both for the absorption and fluorescence spectra. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6Reference of 110590-84-6).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Quinoline and its derivatives are widely used as fungicides, biological agents, antibiotics, alkaloids, dyes, rubber chemicals and flavoring agents. Isoquinoline-type alkaloids show biological activities similar to those of morphinane-, protoberberine-, and benzophenanthridine-type alkaloids.Reference of 110590-84-6

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Original Suzuki-Miyaura Coupling Using Nitro Derivatives for the Synthesis of Perylenediimide-Based Multimers was written by Rocard, Lou;Hatych, Danylo;Chartier, Thomas;Cauchy, Thomas;Hudhomme, Pietrick. And the article was included in European Journal of Organic Chemistry in 2019.SDS of cas: 110590-84-6 This article mentions the following:

A series of perylenediimide (PDI)-based multimers were synthesized using an original Suzuki-Miyaura Coupling (SMC) reaction. The new approach considers the reaction between 1-nitroPDI as the electrophilic reagent with a wide variety of boronic esters to reach PDI dimers, trimers and tetramers which are of particular interest as Non-Fullerene Acceptors (NFAs) in organic photovoltaics. The authors compared the reactivity of 1-bromoPDI and 1-nitroPDI towards this pallado-catalyzed cross-coupling reaction. Considering that 1-nitroPDI is more accessible in terms of selectivity, time reaction, purification efficiency, atom economy, etc, the use of nitroarenes is largely favored in the preparation of these PDI-based multimers. The latter were characterized with determination of their spectroscopic and electrochem. properties. With the aim of extending this SMC reaction to N-annulated PDI analogs, an original and efficient transformation of nitro-PDI into pyrrole-fused PDI was found as an alternative to the known reductive Cadogan cyclization. The SMC reaction was applied to bromo and nitro N-annulated PDI derivatives, and DFT calculations were accomplished to clarify the oxidative addition step of the cross-coupling and understand the difference of reactivity between the bromo- and nitro-PDI based electrophiles. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6SDS of cas: 110590-84-6).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Although isoquinoline derivatives can be synthesized by several methods, relatively few direct methods deliver the unsubstituted isoquinoline. Isoquinoline-type alkaloids show biological activities similar to those of morphinane-, protoberberine-, and benzophenanthridine-type alkaloids.SDS of cas: 110590-84-6

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Synthesis of a Donor-Acceptor Diblock Copolymer via Two Mechanistically Distinct, Sequential Polymerizations Using a Single Catalyst was written by Ono, Robert J.;Todd, Alexander D.;Hu, Zhongjian;Vanden Bout, David A.;Bielawski, Christopher W.. And the article was included in Macromolecular Rapid Communications in 2014.SDS of cas: 110590-84-6 This article mentions the following:

Treatment of a Ni-terminated poly(3-hexylthiophene) (P3HT), generated in situ from 5-chloromagnesio-2-bromo-3-hexylthiophene and Ni(1,3-bis(diphenylphosphino)propane)Cl₂, with a perylene diimide-functionalized arylisocyanide monomer effects a chain-extension polymerization to afford a donor-acceptor diblock copolymer using a single catalyst and in a single reaction vessel. The two mechanistically distinct polymerizations proceed in a controlled, chain growth fashion, allowing the mol. weight of both the P3HT and poly(isocyanide) blocks to be tuned by adjusting the initial monomer-to-catalyst ratios. The resulting materials are found to self-assemble into crystalline, lamellar stacks of donor and acceptor components in the solid state, and also exhibit fluorescence quenching in thin films, properties which poise these materials for use in organic photovoltaic applications. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6SDS of cas: 110590-84-6).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Quinoline is a mancude organic heterobicyclic parent, an azaarene, an ortho-fused heteroarene and a member of isoquinolines. Lewis acid activation and nucleophilic attack can produce multiple regioisomers in quinolines and pyridines; isoquinolines generally only undergo attack at the 1-position.SDS of cas: 110590-84-6

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Improved performance of perylenediimide-based lasers was written by Ramirez, Manuel G.;Morales-Vidal, Marta;Navarro-Fuster, Victor;Boj, Pedro G.;Quintana, Jose A.;Villalvilla, Jose M.;Retolaza, Aritz;Merino, Santos;Diaz-Garcia, Maria A.. And the article was included in Journal of Materials Chemistry C: Materials for Optical and Electronic Devices in 2013.Name: 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone This article mentions the following:

The aim of this work was to improve the laser performance, in terms of threshold and operational lifetime, of lasers based on polymer films doped with perylenediimide (PDI) derivatives as active media. For such purpose, the authors 1st studied the amplified spontaneous emission (ASE) properties of perylene orange (PDI-O), when doped into polystyrene (PS) films. Lower ASE thresholds and larger photostabilities than those of similar films containing another PDI derivative (PDI-C6), recently reported in the literature, were measured. Results were interpreted in terms of the photoluminescence efficiency of the films, which depends on the type of mol. arrangement, inferred with the help of NMR experiments Also PS films have a better ASE performance, i.e. lower thresholds and larger photostabilities, than those based on PMMA, which was recently highlighted as 1 of the best matrixes for PDI-O. Finally, a 1-dimensional 2nd-order distributed feedback laser using PS doped with PDI-O was fabricated and characterized. This device showed a threshold significantly lower (by around 1 order of magnitude) than that of a similar laser based on PDI-C6-doped PS. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6Name: 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Being an analog of pyridine, isoquinoline is a weak base, with a pKa of 5.14. Other industrial applications include their use as corrosion inhibitors, preservatives, and as solvents for resins and terpenes.Name: 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Perylene dyes with high resistance to alkali was written by Langhals, Heinz;Jaschke, Harald;Bastani-Oskoui, Haleh;Speckbacher, Markus. And the article was included in European Journal of Organic Chemistry in 2005.Formula: C50H62N2O4 This article mentions the following:

The attachment of a 纬-hydroxy alkyl group to a nitrogen atom of perylene-3,4:9,10-tetracarboxylic bisimides results in a persistency to alk. hydrolysis, even to alkali alcoholates. The solubility of these dyes can be controlled by substituents in the 尾-position of the alkyl groups so that either highly stable pigments or dyes for homogeneous solutions with high fluorescence quantum yields are obtained. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6Formula: C50H62N2O4).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Although isoquinoline derivatives can be synthesized by several methods, relatively few direct methods deliver the unsubstituted isoquinoline. Most traditional methods of generating isoquinoline do so via oxidative aromatization of dihydro- or tetrahydro-isoquinolines, usually offering some environmental or economic advantage.Formula: C50H62N2O4

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Two asymmetrical perylene diimide derivatives: Synthesis, optical-electrochemical properties and morphologies of self-assembly was written by Tao, Jiayu;Zhang, Jiuxuan;Song, Yuting;Liu, Jian;Xu, Hai-Jun. And the article was included in Journal of Solid State Chemistry in 2022.Synthetic Route of C50H62N2O4 This article mentions the following:

In this manuscript, two PDI derivatives I [X = N] and I [X = O] with unsym. N-substitution of amine and ester-bridge were designed and synthesized. These two compounds were characterized by NMR, Fourier transform IR (FT-IR), and high-resolution mass spectrometry (HRMS). The photophys. properties were studied by UV-Vis absorption and fluorescence spectroscopy. Cyclic voltammograms of I [X = N] and I [X = O] were investigated and HOMO and LUMO energy levels of both two PDIs were estimated as -6.2 and -3.9 eV, resp. Thermal properties were also studied by thermogravimetric anal. (TGA) and differential scanning calorimetry (DSC). I [X = N] was assembled into nanotubes while I [X = O] was assembled into nanobelts resp., via a reprecipitation method. I [X = N] and I [X = O] show good potential application in organic devices such as solar cells, organic field-effect transistors (OFETs) and so on. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6Synthetic Route of C50H62N2O4).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Isoquinoline is a structural isomer of quinoline, which have antiseptic, antipyretic and anti-cyclic properties, and can be used as antimalarial drugs and for the preparation of other antimalarial medicine. It protonates to form salts upon treatment with strong acids, such as HCl. It forms adducts with Lewis acids, such as BF3.Synthetic Route of C50H62N2O4

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Twisted Molecular Nanoribbons with up to 53 Linearly-Fused Rings was written by Dubey, Rajeev K.;Melle-Franco, Manuel;Mateo-Alonso, Aurelio. And the article was included in Journal of the American Chemical Society in 2021.Computed Properties of C50H62N2O4 This article mentions the following:

The synthesis of three mol. nanoribbons with a twisted aromatic framework is described. The largest one shows a 53 linearly fused rings backbone (12.9 nm) and 322 conjugated atoms in its aromatic core (C₂₉₆N₂₄S₂). This new family of nanoribbons shows extremely high molar absorptivities, reaching 986 100 M^-1 cm^-1, and red-emitting properties. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6Computed Properties of C50H62N2O4).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Quinoline is a catabolite of tryptophan, the basic structure of some antihypertensive drugs, such as the peripheral vasodilators prazosin and doxazosin. Lewis acid activation and nucleophilic attack can produce multiple regioisomers in quinolines and pyridines; isoquinolines generally only undergo attack at the 1-position.Computed Properties of C50H62N2O4

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Directly linked zinc phthalocyanine-perylenediimide dyads and a triad for ultrafast charge separation was written by Zink-Lorre, Nathalie;Font-Sanchis, Enrique;Seetharaman, Sairaman;Karr, Paul A.;Sastre-Santos, Angela;D鈥睸ouza, Francis;Fernandez-Lazaro, Fernando. And the article was included in Chemistry – A European Journal in 2019.Safety of 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone This article mentions the following:

Directly linked to promote strong intramol. interactions, donor-acceptor dyads and a donor-acceptor-donor triad featuring zinc phthalocyanine (ZnPc) as electron donor and perylenediimide (PDI) as electron acceptor have been synthesized and characterized. Owing to complementary absorption features of the entities, improved light absorption was witnessed in these conjugates. The optimized geometry and electronic structures showed the majority of the HOMO (HOMO) on the ZnPc entity, whereas the LUMO (LUMO) was on the PDI entity, suggesting that the charge-separated states would be ZnPc⁺-PDI^.-. The electrochem. and free-energy calculations suggested exothermic energy and/or electron transfer processes via the singlet states of PDI or ZnPc entities depending on the excitation wavelength of the laser used. The measured rates using femtosecond pump-probe spectroscopy coupled with global anal. of transient data revealed ultrafast energy transfer from ¹PDI* to ZnPc followed by charge separation However, when ZnPc was selectively excited, only electron transfer was witnessed wherein the time constants for forward and reverse electron transfer processes followed Marcus predictions. The absorption in a wide section of the solar spectrum and the ultrafast charge separation suggest the usefulness of these systems as good photosynthetic models. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6Safety of 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Although isoquinoline derivatives can be synthesized by several methods, relatively few direct methods deliver the unsubstituted isoquinoline. Other industrial applications include their use as corrosion inhibitors, preservatives, and as solvents for resins and terpenes.Safety of 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Novel dithiano-thieno fused perylene diimides: synthesis, characterization and application in organic thin-film transistors (OTFTs) was written by Li, Gang;Li, Dandan;Liu, Xitong;Xu, Haixiao;Zhang, Jing;Wang, Shuaihua;Liu, Zhenhua;Tang, Bo. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Category: isoquinoline This article mentions the following:

Three novel perylene diimides featuring [1,2]dithiine and sulfur annulation onto the PDI core and different branched alkyl chains have been designed and facilely synthesized. The organic thin-film transistor (OTFT) devices based on the as-synthesized compounds showed maximum electron mobilities of up to 0.008 cm² V^-1 s^-1 under an ambient atm. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6Category: isoquinoline).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. The isoquinoline structure occurs in a considerable number of alkaloids in widely separated plant families. Other industrial applications include their use as corrosion inhibitors, preservatives, and as solvents for resins and terpenes.Category: isoquinoline

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Interactions of Perylene Bisimide in the One-Dimensional Channels of Zeolite L was written by Busby, Michael;Devaux, Andre;Blum, Christian;Subramaniam, Vinod;Calzaferri, Gion;De Cola, Luisa. And the article was included in Journal of Physical Chemistry C in 2011.COA of Formula: C50H62N2O4 This article mentions the following:

Supramolecularly organized host guest systems were prepared by inserting three perylene dyes with differing end substituents into the nanosized channels of zeolite L (ZL) by gas-phase adsorption under vacuum conditions. The end substituents allowed controlling the core-to-core distances of the mols. in the channels. The three perylene dyes studied have very similar absorption and fluorescence spectra in diluted solutions, as well as fluorescence lifetimes 鈭?4 ns. Large ZL crystals in the size range of 1500-3000 nm in length and 鈭?000 nm in diameter as well as nanosized NZL crystals of 鈭?0 nm in length and diameter were used as hosts. Different loadings were studied. The photophys. properties of the materials were analyzed as suspensions in refractive index matching solvents, such as toluene or Et benzoic acid ester; as bulk materials in glass ampuls; and by time-, space-, and spectrally resolved single-crystal fluorescence microspectrocopy techniques. The inserted dyes can form J-aggregates if the structure of the perylene derivative allows for short distances between the electronic transition moments in an in-line arrangement. J-coupling was not seen for the mols. with substituents that keep them further apart. Aligned and stabilized J-aggregates in 1-dimensional channels provide new options for preparing optical devices, where coherent exciton delocalization over nanometer-to-micrometer scales may result in efficient photonic wires. The exciton coupling can be controlled by varying the mol. tail groups. In the experiment, the researchers used many compounds, for example, 2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6COA of Formula: C50H62N2O4).

2,9-Di(tridecan-7-yl)anthra[2,1,9-def:6,5,10-d’e’f’]diisoquinoline-1,3,8,10(2H,9H)-tetraone (cas: 110590-84-6) belongs to isoquinoline derivatives. Being an analog of pyridine, isoquinoline is a weak base, with a pKa of 5.14. They are also used to make oil-soluble dyes, food colorants, pharmaceuticals, pH indicators and other organic compounds. COA of Formula: C50H62N2O4

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem