Category: 1532-97-4

In a broader sense, the term isoquinoline is used to make reference to isoquinoline derivatives. 1-Benzylisoquinoline is the structural backbone in naturally occurring alkaloids including papaverine. 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. The isoquinoline ring in these natural compound derives from the aromatic amino acid tyrosine. Product Details of C9H6BrN.

Xu, Dan;Zhao, Hong;Dong, Zhengping;Ma, Jiantai research published 《 Catalytically Active Co-N_x Species Stabilized on Nitrogen-doped Porous Carbon for Efficient Hydrogenation and Dehydrogenation of N-heteroarenes》, the research content is summarized as follows. A highly dispersed cobalt catalyst stabilized on the mesoporous N-doped carbon layers was prepared by adsorption and pyrolysis of cobalt complex on dendritic fibrous silica nanospheres (KCC-1@Co-N-C-T)was studied. The characterizations of HAADF-STEM, XRD and XPS together with the KSCN poisoning tests determine the absence of Co⁰ or CoO_x nanoparticles and the Co-N_x species were the active sites. The formation of Co-N_x species resulted from the properties of N-rich cobalt-phenanthroline complex and dendritic fibrous silica supports, increased the original spatial distance between Co atoms and thus prevented them from aggregation. The KCC-1@Co-N-C-800 catalyst showed excellent activity and selectivity for the oxidative dehydrogenation (ODH) of saturated N-heterocycles and base-free catalytic transfer hydrogenation (CTH) of unsaturated N-heterocycles.

Product Details of C9H6BrN, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., 1532-97-4.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

In a broader sense, the term isoquinoline is used to make reference to isoquinoline derivatives. 1-Benzylisoquinoline is the structural backbone in naturally occurring alkaloids including papaverine. 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. The isoquinoline ring in these natural compound derives from the aromatic amino acid tyrosine. Synthetic Route of 1532-97-4.

Xu, Pin;Chen, Peng-Yu;Xu, Hai-Chao research published 《 Scalable Photoelectrochemical Dehydrogenative Cross-Coupling of Heteroarenes with Aliphatic C-H Bonds》, the research content is summarized as follows. Heteroarenes are structural motifs found in many bioactive compounds and functional materials. Dehydrogenative cross-coupling of heteroarenes with aliphatic C-H bonds provides straightforward access to functionalized heteroarenes from readily available materials. Established methods employ stoichiometric chem. oxidants under conditions of heating or light irradiation By merging electrochem. and photochem., we have achieved efficient photoelectrochem. dehydrogenative cross-coupling of heteroarenes and C(sp³)-H donors through H₂ evolution, without the addition of metal catalysts or chem. oxidants. Mechanistically, the C(sp³)-H donor is converted to a nucleophilic carbon radical through H-atom transfer with chlorine atom, which is produced by light irradiation of anodically generated Cl₂ from Cl^–. The carbon radical then undergoes radical substitution to the heteroarene to afford alkylated heteroarene products.

Synthetic Route of 1532-97-4, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., 1532-97-4.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

In a broader sense, the term isoquinoline is used to make reference to isoquinoline derivatives. 1-Benzylisoquinoline is the structural backbone in naturally occurring alkaloids including papaverine. 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. The isoquinoline ring in these natural compound derives from the aromatic amino acid tyrosine. Application of C9H6BrN.

Yadav, Lalit;Tiwari, Mohit K.;Shyamlal, Bharti Rajesh Kumar;Chaudhary, Sandeep research published 《 Organocatalyst in Direct C(_sp²)-H Arylation of Unactivated Arenes: [1-(2-Hydroxyethyl)-piperazine]-Catalyzed Inter-/Intra-molecular C-H Bond Activation》, the research content is summarized as follows. In the presence of 10 mol% 1-piperazineethanol, aryl iodides and bromides underwent arylation with benzene mediated by KOt-Bu to yield biaryls. N-Aryl 2-bromobenzamides underwent cyclization mediated by KOt-Bu in the presence of 40 mol% 1-piperazineethanol and 40 mol% 4-dimethylaminopyridine in mesitylene to yield phenanthridinones. Study of the reaction mechanism using kinetics and kinetic isotope effects and inhibition studies are consistent with the formation of aryl radical anions and a single electron transfer mechanism.

Application of C9H6BrN, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., 1532-97-4.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Isoquinoline’s properties: Isoquinoline is a colorless hygroscopic liquid at temperatures above its melting point with a penetrating, 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. unpleasant odor. Impure samples can appear brownish, as is typical for nitrogen heterocycles. Formula: C9H6BrN.

Yang, Xu-Wen;Li, Dong-Hui;Song, A-Xiang;Liu, Feng-Shou research published 《 ”Bulky-Yet-Flexible” α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air》, the research content is summarized as follows. To pursue a highly regioselective and efficient reductive Heck reaction, a series of moisture- and air-stable α-diimine palladium precatalysts was rationally designed, readily synthesized, and fully characterized. The relationship between the structures of the palladium complexes and the catalytic properties was investigated. It was revealed that the “bulky-yet-flexible” palladium complexes allowed highly anti-Markovnikov-selective hydroarylation of alkenes with (hetero)aryl bromides under aerobic conditions. Further, synthetic application of the present protocol could provide rapid and straightforward access to functional and biol. active mols.

Formula: C9H6BrN, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., 1532-97-4.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Isoquinoline’s properties: Isoquinoline is a colorless hygroscopic liquid at temperatures above its melting point with a penetrating, 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. unpleasant odor. Impure samples can appear brownish, as is typical for nitrogen heterocycles. Name: 4-Bromoisoquinoline.

Zhang, Dong;Cai, Jinlin;Du, Jinze;Wang, Qingdong;Yang, Jinming;Geng, Rongqing;Fang, Zheng;Guo, Kai research published 《 Electrochemical-Oxidation-Promoted Direct N-ortho-Selective Difluoromethylation of Heterocyclic N-Oxides》, the research content is summarized as follows. An efficient and green electrochem. N-ortho-selective difluoromethylation method of various quinoline and isoquinoline N-oxides has been developed. In this method sodium difluoromethanesulfinate (HCF₂SO₂Na) was used as the source of difluoromethyl moiety and various N-ortho-selective difluoromethylation quinolines and isoquinolines N-oxides were obtained in good to excellent yield under constant current. In addition, the reaction was easy to scale up and maintains good yields. Preliminary mechanism studies suggested that the reaction has underwent a free radical addition and hydrogen elimination pathway.

Name: 4-Bromoisoquinoline, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., 1532-97-4.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

In a broader sense, the term isoquinoline is used to make reference to isoquinoline derivatives. 1-Benzylisoquinoline is the structural backbone in naturally occurring alkaloids including papaverine. 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. The isoquinoline ring in these natural compound derives from the aromatic amino acid tyrosine. COA of Formula: C9H6BrN.

Zhang, Jun-Qi;Hu, Dandan;Song, Jinyu;Ren, Hongjun research published 《 [3+2]-Annulation of gem-Difluoroalkenes and Pyridinium Ylides: Access to Functionalized 2-Fluoroindolizines》, the research content is summarized as follows. A [3+2]-annulation of gem-difluoroalkenes and pyridinium ylides was developed employing ambient air as the sole oxidant in an open-vessel manner, which afforded a series of multifunctionalized 2-fluoroindolizines in moderate to good yields. Gem-difluoroalkene acted as a C2 synthon and entirely avoided the competitive addition-elimination process, which provideed facile access to 2-fluoroindolizines.

COA of Formula: C9H6BrN, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., 1532-97-4.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Isoquinoline is a heterocyclic aromatic organic compound. 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. It is a structural isomer of quinoline. Isoquinoline and quinoline are benzopyridines, which are composed of a benzene ring fused to a pyridine ring. HPLC of Formula: 1532-97-4.

Zhao, Jianhong;Qian, Kun;Tong, Mengchao;Yuan, Qiyang;Zhang, Yongqiang research published 《 Mild and Metal-Free Cross-Dehydrogenative Coupling of Nitrogen Heteroarenes with Aldehydes Enabled by Structural Hybridization of Promoting Reagents》, the research content is summarized as follows. A mild and metal-free cross-dehydrogenative coupling reaction of nitrogen heteroarenes with aldehydes has been developed by the structural hybridization of promoting reagents. The procedure is environmentally benign, cost-effective and industrially scalable, which allows the direct acylation of electron-deficient nitrogen heteroarenes in moderate to good yields. Furthermore, the synthetic utility of this new method in the synthesis of a variety of pharmaceutically relevant isoquinoline alkaloids has been also demonstrated.

1532-97-4, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., HPLC of Formula: 1532-97-4

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Isoquinoline can crystallizes in platelets that have a low solubility in water but dissolve well in ethanol, acetone, diethyl ether, carbon disulfide, and other common organic solvents. 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. It is also soluble in dilute acids as the protonated derivative. Category: isoquinoline.

Zheng, Zhongqi;Wu, Yongdi;Lu, Xuelian;Zhang, Fang-Lin;Qi, Mei-Fang;Sun, Enjie;Sun, Bing research published 《 Visible-light-mediated metal-free decarboxylative acylation of electron-deficient quinolines using α-ketoacids under ambient air》, the research content is summarized as follows. A visible-light-promoted metal-free decarboxylative coupling protocol for the acylation of electron-deficient quinolines RH [R = quinolin-1-yl, 6-nitroquinolin-1-yl, 3-methylquinolin-1-yl, etc.] using ambient air as an oxidant has been disclosed. This environmental-friendly protocol takes place under mild conditions and is highlighted by using inexpensive photocatalyst and starting materials, thereby integrating C-H functionalization and recent photoredox scenario based on diaryl ketones RC(O)R¹ [R¹ = Ph, Me, thiophen-2-yl, etc.]. This work contributes to a more systematic utilization of α-ketoacids R¹C(O)OH as an efficient source of acyl radicals in acylation of electron-deficient heteroaromatic compounds

1532-97-4, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., Category: isoquinoline

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Isoquinoline’s properties: Isoquinoline is a colorless hygroscopic liquid at temperatures above its melting point with a penetrating, 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. unpleasant odor. Impure samples can appear brownish, as is typical for nitrogen heterocycles. COA of Formula: C9H6BrN.

Zhou, Youkang;Liu, Wei;Xing, Zhiming;Guan, Jiali;Song, Zhibin;Peng, Yiyuan research published 《 External-photocatalyst-free visible-light-mediated aerobic oxidation and 1,4-bisfunctionalization of N-alkyl isoquinolinium salts》, the research content is summarized as follows. Visible-light-mediated aerobic alternate transformations of N-alkyl isoquinolinium salts I [X = I, Br, BF₄; R = H, OMe, Ph, Cl, Br; R¹ = H, Br, Ph, I; R² = H, Et, naphthalen-1-yl, 2-bromophenyl, etc.] and 2,2′-(butane-1,4-diyl)bis(isoquinolin-2-ium) iodide/quinolinium salts II [R³ = H, Br, Ph, naphthalen-1-yl; R⁴ = H, naphthalen-1-yl, 3-methylphenyl, 2-phenylethyl; R⁵ = H, Ph, Br, OMe, Cl] in the absence of any extra added photocatalyst are reported. Here, a highly concise, sustainable and low-cost protocol to produce unsaturated lactams III/IV and 2,2′-(butane-1,4-diyl)bis(isoquinolin-1(2H)-one) from oxidation of their corresponding isoquinolinium salts I or quinolinium salts II using air as an oxidant was developed. Important building blocks for further modification of biol. active isoquinolones, 4-iodoisoquinolinones III and 2,2′-(butane-1,4-diyl)bis(4-iodoisoquinolin-1(2H)-one) were also produced through 1,4-bisfunctionalization of isoquinolinium salts I without the use of any transition metal. Gram-scale synthesis was achieved under sunlight with exposure to the open air. Mechanism studies suggested that singlet oxygen generation triggered by isoquinolinium salts I/quinolinium salts II under visible light irradiation and trace water may lead to multiple pathways for the aerobic transformations of N-alkyl iminium salts.

1532-97-4, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., COA of Formula: C9H6BrN

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem

Isoquinoline can crystallizes in platelets that have a low solubility in water but dissolve well in ethanol, acetone, diethyl ether, carbon disulfide, and other common organic solvents. 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. It is also soluble in dilute acids as the protonated derivative. SDS of cas: 1532-97-4.

Zhou, Zhong;Ji, Huihui;Li, Qing;Zhang, Qian;Li, Dong research published 《 Direct C-H aminocarbonylation of N-heteroarenes with isocyanides under transition metal-free conditions》, the research content is summarized as follows. A C-C bond forming amide synthesis through direct C-H aminocarbonylation of N-heteroarenes with isocyanides was developed. The reaction was mediated by an inorganic persulfate salt under transition metal-free conditions. Mechanistic studies suggested a radical pathway for this reaction without the participation of H₂O and O₂. This method also showed merits of substrate availability, easy operation and atom economy. It provided an efficient route for straightforward synthesis of N-heteroaryl amides.

1532-97-4, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.

4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., SDS of cas: 1532-97-4

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem