394-67-2, Name is 4-Fluoroisoquinoline, belongs to isoquinoline compound, is a common compound. SDS of cas: 394-67-2In an article, once mentioned the new application about 394-67-2.
Electrophotocatalytic C-H Functionalization of Ethers with High Regioselectivity
The highly regioselective electrophotocatalytic C-H functionalization of ethers is described. These reactions are catalyzed by a trisaminocyclopropenium (TAC) ion at mild electrochemical potential with visible light irradiation. Ethers undergo oxidant-free coupling with isoquinolines, alkenes, alkynes, pyrazoles, and purines with typically high regioselectivity for the less-hindered alpha-position. The reaction is proposed to operate via hydrogen atom transfer (HAT) from the substrate to the photoexcited TAC radical dication, thus demonstrating a new reactivity mode for this electrophotocatalyst.
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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem