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MnO2/TiO2 catalyzed synthesis of coenzyme pyridoxamine-5?-phosphate analogues: 3-deoxypyridoxamine-5?-phosphate
The highly efficient-selective synthetic route of the pyridoxal-5?-phosphate (vitamin B6, PLP) analogues: C3 substituted deoxy derivatives of pyridoxal (PL), pyridoxal-N-oxide (PLNO), pyridoxamine (PM), pyridoxamine-5?-phosphate (PMP) and pyridoxal-5?-phosphate (PLP), were developed via reduction and followed by selective oxidation in one pot using solid supported nanoparticles. The salient features of this strategy are: economic two-fold conversion, more Lewis acid sites, vacancies on the nanoparticle surfaces, and good yields of 3-deoxypyridoxal and 3-deoxypyridoxamine-5?-phosphate.
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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem