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A facile microwave-assisted palladium-catalyzed cyanation of aryl chlorides
We report an efficient method for the preparation of aryl nitriles from aryl chlorides under either microwave assisted or thermal conditions. A catalyst system comprising tris(dibenzylidene acetone)dipalladium (Pd2(dba)3) and 2-(2?,6?-dimethoxybiphenyl)dicyclohexylphosphine (S-Phos) is shown to effectively promote cyanation of various aryl chlorides with Zn(CN)2 as the cyanide source.
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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem