Application of 589-18-4, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 589-18-4, Name is p-Tolylmethanol, SMILES is OCC1=CC=C(C)C=C1, belongs to isoquinoline compound. In a article, author is Fan, X., introduce new discover of the category.
Ni- and Pd/C-catalyzed Hydrodenitrogenation of Isoquinoline
Hydrodenitrogenation (HDN) of isoquinoline (IQ) over Ni and Pd/C were investigated at 200 and 300 degrees C under pressurized hydrogen. The results show that Ni is less active at 200 degrees C but more active at 300 degrees C than Pd/C for HDN of IQ. Raising reaction temperature from 200 to 300 degrees C significantly increased nitrogen removal selectivity. pi-Electrondensity of pyridine ring and cleavage of C-N bond were investigated and found to play important roles in HDN of IQ.
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Reference:
Isoquinoline – Wikipedia,
,Isoquinoline | C9H7N – PubChem