Awesome and Easy Science Experiments about 3-Methylisoquinoline

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Catalytic 1,4-selective hydrosilylation of pyridines and benzannulated congeners

Radically different! The hydrosilylation of pyridines and quinolines is strictly 1,4-selective and likely involves an ionic one-step rather than the established radical two-step hydride transfer from a ruthenium(II) hydride complex onto the respective pyridinium and quinolinium ion intermediates (see scheme; ArF=3,5-(CF3)2C6H 3). Even 4-substituted substrates react highly regioselectively. Isoquinolines yield the 1,2-reduced heterocycles.

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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem