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Formal Insertion of Imines (or Nitrogen Heteroarenes) and Arynes into the C-Cl Bond of Carbon Tetrachloride
The formal insertion of double and triple bonds into the C-Cl bond of carbon tetrachloride has enabled the full utilization of carbon tetrachloride in chemical synthesis. A range of unactivated imines and electron-deficient nitrogen heteroarenes served as effective sources of C=N bonds to react with arynes and carbon tetrachloride to afford functionalized anilines whose core structures are present in some valuable arthropodicides. Control experiments and DFT calculations suggest the involvement of a trichloromethyl anion intermediate.
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Reference：
Isoquinoline – Wikipedia,
Isoquinoline | C9H3586N – PubChem