Some scientific research about 6,7-Dimethoxy-3,4-dihydroisoquinoline

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The stereoselective synthesis of (-)-protoemetinol has been accomplished through nine steps from a known homoallylic amine. The key steps of the synthesis involve the efficient preparation of an aza-Claisen rearrangement (ACR) precursor using cross metathesis and amide enolate-induced ACR followed by acid-catalyzed transannulation for the elaboration of the benzo[alpha]quinolizine skeleton and three stereogenic centers. This unique synthetic route envisages a unified and versatile strategy for the synthesis of 2,3-disubstituted benzo[alpha]quinolizidine.

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Reference：
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem