The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Methyl 5-methoxyindole-2-carboxylate, is researched, Molecular C11H11NO3, CAS is 67929-86-6, about [Fe(F20TPP)Cl] catalyzed intramolecular C-N bond formation for alkaloid synthesis using aryl azides as nitrogen source, the main research direction is indole alkaloid synthesis intramol cyclization porphyrin iron catalyst; tetrahydroquinoline alkaloid synthesis intramol cyclization porphyrin iron catalyst; dihydroquinazolinone alkaloid synthesis intramol cyclization porphyrin iron catalyst; quinazolinone alkaloid synthesis intramol cyclization porphyrin iron catalyst.Electric Literature of C11H11NO3.
The syntheses of alkaloids including indoles, indolines, tetrahydroquinolines, dihydroquinazolinones and quinazolinones were accomplished in moderate to excellent yields via [Fe(F20TPP)Cl] (I) catalyzed intramol. C-N bond formation using aryl azides as nitrogen source. E.g., dihydroquinazolinone derivative II was prepared with 83% yield by refluxing N3-2-C6H4CON(CH2Ph)2 with I in (ClCH2)2.
The article 《[Fe(F20TPP)Cl] catalyzed intramolecular C-N bond formation for alkaloid synthesis using aryl azides as nitrogen source》 also mentions many details about this compound(67929-86-6)Electric Literature of C11H11NO3, you can pay attention to it, because details determine success or failure
Reference:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem