Category: isoquinoline. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Diphenyl-2-pyridylphosphine, is researched, Molecular C17H14NP, CAS is 37943-90-1, about A stable well-defined copper hydride cluster consolidated with hemilabile phosphines. Author is Yuan, Shang-Fu; Luyang, Heng-Wang; Lei, Zhen; Wan, Xian-Kai; Li, Jiao-Jiao; Wang, Quan-Ming.
Cu hydrides are very useful in hydrogenation reactions. The authors report a stable Stryker-type Cu hydride reagent protected by hemilabile phosphines: [Cu8H6(dppy)6](OTf)2 (Cu8-H, dppy = diphenylphosphino-2-pyridine). The metal core of this cluster has a bicapped octahedral configuration, and the Cu-bound hydrides each triply bridges over a triangular face of the octahedron. This cluster is attractive due to its facile preparation and excellent stability under ambient conditions. The comparable activity and selectivity both in the stoichiometric and catalytic reactions make Cu8-H a promising alternative to Stryker’s reagent.
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Reference:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem