Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 37943-90-1, is researched, Molecular C17H14NP, about Synthesis, characterization, and electrochemistry of monophosphine-containing diiron propane-1,2-dithiolate complexes related to the active site of [FeFe]-hydrogenases, the main research direction is iron carbonyl propanedithiolate phosphine complex preparation redox potential; crystal structure iron carbonyl propanedithiolate phosphine complex.Related Products of 37943-90-1.
Five monophosphine-substituted diiron propane-1,2-dithiolate complexes as the active site models of [FeFe]-hydrogenases were synthesized and characterized. Reactions of [Fe2(CO)6[μ-SCH2CHMeS]] (1) with a monophosphine ligand tris(4-methylphenyl)phosphine, diphenyl-2-pyridylphosphine, tris(4-chlorophenyl)phosphine, triphenylphosphine, or tris(4-fluorophenyl)phosphine in the presence of the oxidative agent Me3NO·2H2O gave the monophosphine-substituted diiron complexes [Fe2(CO)5(L){μ-SCH2CHMeS}] [L = P(4-C6H4CH3)3, 2; Ph2P(2-C5H4N), 3; P(4-C6H4Cl)3, 4; PPh3, 5; P(4-C6H4F)3, 6] in 81%-94% yields. Complexes 2-6 were characterized by elemental anal., spectroscopy, and x-ray crystallog. Electrochem. studies revealed that these complexes can catalyze the reduction of protons to H2 in the presence of HOAc.
Different reactions of this compound(Diphenyl-2-pyridylphosphine)Related Products of 37943-90-1 require different conditions, so the reaction conditions are very important.
Reference:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem