The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Diphenyl-2-pyridylphosphine(SMILESS: P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=NC=CC=C3,cas:37943-90-1) is researched.Application In Synthesis of (1S,2S)-2-Aminocyclohexanol. The article 《Phosphination of Phenol Derivatives and Applications to Divergent Synthesis of Phosphine Ligands》 in relation to this compound, is published in Organic Letters. Let’s take a look at the latest research on this compound (cas:37943-90-1).
The authors describe a general and efficient protocol for the synthesis of organophosphine compounds from phenols and phosphines (R2PH) via a metal-free C-O bond cleavage and C-P bond formation process. This approach exhibits broad substrate scope and excellent functional group tolerance. The synthetic utilities of this protocol were demonstrated by the synthesis of chiral ligands via the various transformations of cyano groups and their applications in asym. catalysis.
《Phosphination of Phenol Derivatives and Applications to Divergent Synthesis of Phosphine Ligands》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Diphenyl-2-pyridylphosphine)Synthetic Route of C17H14NP.
Reference:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem