McGillicuddy, Ryan D. published the artcileMetal-Organic Phase-Change Materials for Thermal Energy Storage, Recommanded Product: 1-Methylurea, the main research area is phase change material thermal energy storage metal organic.
The development of materials that reversibly store high densities of thermal energy is critical to the more efficient and sustainable utilization of energy. Herein, we investigate metal-organic compounds as a new class of solid-liquid phase-change materials (PCMs) for thermal energy storage. Specifically, we show that isostructural series of divalent metal amide complexes featuring extended hydrogen bond networks can undergo tunable, high-enthalpy melting transitions over a wide temperature range. Moreover, these coordination compounds provide a powerful platform to explore the specific factors that contribute to the energy d. and entropy of metal-organic PCMs. Through a systematic anal. of the structural and thermochem. properties of these compounds, we investigated the influence of coordination bonds, hydrogen-bond networks, neutral organic ligands, and outer-sphere anions on their phase-change thermodn. In particular, we identify the importance of high densities of coordination bonds and hydrogen bonds to achieving a high PCM energy d., and we show how metal-dependent changes to the local coordination environment during melting impact the entropy and enthalpy of metal-organic PCMs. These results highlight the potential of manipulating order-disorder phase transitions in metal-organic materials for thermal energy storage.
Journal of the American Chemical Society published new progress about Bond length. 598-50-5 belongs to class isoquinoline, name is 1-Methylurea, and the molecular formula is C2H6N2O, Recommanded Product: 1-Methylurea.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem