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DEOXYGENATIVE 2-ALKOXYLATION OF QUINOLINE 1-OXIDE
Treatment of quinoline 1-oxide (1) with ethyl chloroformate or tosyl chloride and triethylamine in some lower alcohols affords the corresponding 2-alkoxyquinolines (2a-f) in generally satisfactory yields.Reactions of 2-methylpyridine and 2-methylquinoline 1-oxides lead to the corresponding 2-ethoxycarbonyloxymethyl (3 and 5) and 2-ethoxymethyl derivatives (4 and 6).
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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem