58794-09-5, In an article, published in an article,authors is Chen, Dongping, once mentioned the application of 58794-09-5, Name is 7-Bromoisoquinoline,molecular formula is C9H6BrN, is a conventional compound. this article was the specific content is as follows.
Practical and Asymmetric Reductive Coupling of Isoquinolines Templated by Chiral Diborons
We herein describe a chiral diboron-templated highly diastereoselective and enantioselective reductive coupling of isoquinolines that provided expedited access to a series of chiral substituted bisisoquinolines in good yields and excellent ee’s under mild conditions. The method enjoys a broad substrate scope and good functional group compatibility. Mechanistic investigation suggests the reaction proceeds through a concerted [3,3]-sigmatropic rearrangement.
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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem