Archives for Chemistry Experiments of 486-73-7

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Synthetic Route of 486-73-7, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.486-73-7, Name is Isoquinoline-1-carboxylic acid, molecular formula is C10H7NO2. In a Article£¬once mentioned of 486-73-7

The crystal and molecular structure of chlorotriphenyl(isoquinolinium-1-carboxylato)tin(IV)

The synthesis and crystal structure of the 1:1 complex formed between triphenyltin chloride and isoquinoline-1-carboxylic acid () is described.The tin(IV) atom is found to be five coordinate, being bound to three phenyl groups, the chlorine atom, and an oxygen from isoquinoline-1-carboxylic acid.The geometry around the tin atom is that of a trigonal bipyramid, with the three phenyl groups occupiyng the equatorial positions, and the apical sites taken by the chlorine atom and a carboxyl oxygen from the isoquinoline-1-carboxylic acid.The crystals are triclinic, space group P<*>, with a=17.932(12) Angstroem, b=17.935(15) Angstroem, c=18.686(12) Angstroem, alpha=63.16(5) deg, beta=81.70(6) deg, gamma=68.45(6) deg, V=4986(6)(10) Angstroem3, Z=8, and Dcalc=1.486 Mg m-3.The final residual is RF=0.050, on 8375 reflections with Inet>2.5?(Inet).Two of the cell dimensions are equivalent and there are four molecular units in the unit cell, so precausions are described for ensuring that correct space-group determination had been made and that some concealed symmetry in the final structure had not been overlooked.Key words: triorganotin, complex, isoquinoline-1-carboxylic acid, fungicidal activity.

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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem