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Preparation of polyfunctional zinc organometallics using an Fe- or Co-catalyzed Cl/Zn-exchange

A new Fe- or Co-catalyzed Cl/Zn-exchange reaction allows the direct transformation of aryl, heteroaryl, and also alkyl chlorides into the corresponding zinc reagents. The method tolerates functional groups such as a nitrile or an ester. Remarkably, secondary and tertiary alkyl chlorides are suitable substrates for the Cl/Zn exchange.

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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem