Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 21806-61-1, Name is Prop-1-ene-1,3-sultone, SMILES is O=S1(C=CCO1)=O, in an article , author is Barman, Piyali Deb, once mentioned of 21806-61-1, Recommanded Product: Prop-1-ene-1,3-sultone.
Cu(OTf)(2)-promoted efficient synthetic route towards glycospiro-pyrrolo[2,1-a]isoquinolines
A simple, convenient and efficient protocol for the construction of an array of glycospiro-pyrroloisoquinolines using isoquinolinium ylide and a carbohydrate-derived exocyclic olefin in the presence of Cu(OTf)(2)-Et3N catalytic system is described. Isoquinoline and alkylbromoacetates/2-bromoacetophenones were employed to generate the azomethine ylides in the presence of Et3N in refluxing toluene and subsequent exposure to the olefin led to the desired isoquinoline derivatives. (C) 2014 Elsevier Ltd. All rights reserved.
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Reference:
Isoquinoline – Wikipedia,
,Isoquinoline | C9H7N – PubChem