Awesome Chemistry Experiments For 1-(Isoquinolin-1-yl)ethanone

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Transition-Metal-Free Radical Hydrotrifluoromethylation of Alkynes

A combination of readily available and bench-stable CF3SO2Na and tBuOOH was efficiently used for hydrotrifluoromethylation of alkynes. An excellent trans-selectivity was demonstrated in the synthesis of alkenes. The developed mild reaction conditions allow the supression of the competing Meyer?Schuster-type rearrangement.

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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H1617N – PubChem