Chemistry is traditionally divided into organic and inorganic chemistry. Recommanded Product: 58794-09-5, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent，Which mentioned a new discovery about 58794-09-5
The dearomatizing annulation reaction is a significant challenge in organic chemistry. The direct activation of alpha-carbons of simple saturated esters, as nucleophiles, is an important synthesis strategy. In the present study, we disclose [3 + 2] dearomatizing annulation reactions with direct activating alpha-carbons of saturated carboxylic esters and N-iminoisoquinolinium ylides, which possess highly enantioselective characteristics, catalyzed by N-heterocyclic carbenes (NHCs). The protocol achieves isoquinoline dearomatization and the construction of tricyclic chiral products under mild conditions with good yield, substrate tolerance, and diastereoselectivity as well as excellent enantioselectivity.
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Reference：
Isoquinoline – Wikipedia,
Isoquinoline | C9H3703N – PubChem