In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Recommanded Product: 486-73-7, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 486-73-7, name is Isoquinoline-1-carboxylic acid. In an article，Which mentioned a new discovery about 486-73-7
Herein, we report a Cu-catalyzed enantioselective allylic alkylation using a gamma-butyrolactone-derived silyl ketene acetal. Critical to the development of this work was the identification of a novel mono-picolinamide ligand with the appropriate steric and electronic properties to afford the desired products in high yield (up to 96 %) and high ee (up to 95 %). Aryl, aliphatic, and unsubstituted allylic chlorides bearing a broad range of functionality are well-tolerated. Spectroscopic studies reveal that a CuI species is likely the active catalyst, and DFT calculations suggest ligand sterics play an important role in determining Cu coordination and thus catalyst geometry.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 486-73-7, help many people in the next few years.Recommanded Product: 486-73-7
Reference：
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem