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This review focuses on direct C?H bond functionalization reactions of N-heteroaromatic compounds by group 3 and 4 organometallic complexes. Early transition-metal-carbon and -nitrogen bonds are highly reactive to C?H bond activation via a sigma-bond metathesis pathway to form new organometallic species. By further inserting other unsaturated molecules into the new metal-carbon bond, C?H bond functionalized products are selectively obtained. To clarify the reaction mechanism, we categorize the reaction by the chelation size of the metallacycle intermediate generated from the organometallic species with N-heteroaromatic compounds, and include both stoichiometric and catalytic reactions with their reaction mechanism.
We’ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 1125-80-0, and how the biochemistry of the body works.Reference of 1125-80-0
Reference：
Isoquinoline – Wikipedia,
Isoquinoline | C9H119N – PubChem