The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Diphenyl-2-pyridylphosphine(SMILESS: P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=NC=CC=C3,cas:37943-90-1) is researched.Recommanded Product: 5-Bromo-3-methoxypyridin-2-amine. The article 《Blue luminescent silver(I) complexes constructed by 2-diphenylphosphinopyridine and dicyanamide or tricyanomethanide》 in relation to this compound, is published in Inorganic Chemistry Communications. Let’s take a look at the latest research on this compound (cas:37943-90-1).
Two new silver(I) complexes 2-diphenylphosphinopyridine (dppy), {Ag2(dppy)2[N(CN)2]}2[μ-N(CN)2]2 (1) and {Ag2(dppy)2[μ-C(CN)3]2}n (2) linked by dicyanamide (N(CN)-2) or tricyanomethanide (C(CN)-3) were synthesized and characterized by x-ray crystallog. Complex 1 forms a tetranuclear structure with two binucleate moieties [Ag2(dppy)2]+ linked by two dicyanamide ligands. Interestingly, when bridging ligand is changed to tricyanomethanide, complex 2 displays one-dimensional infinite chain structure. Both complexes exhibit strong blue emission with phosphorescent quantum yields of 13.4% for 1 and 39.2% for 2 in solid state.
I hope my short article helps more people learn about this compound(Diphenyl-2-pyridylphosphine)Formula: C17H14NP. Apart from the compound(37943-90-1), you can read my other articles to know other related compounds.
Reference:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem