Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Research Support, N.I.H., Extramural, Research Support, U.S. Gov’t, Non-P.H.S., Journal of the American Chemical Society called Catalytic Enantioselective Allylation of Dienals through the Intermediacy of Unsaturated π-Allyl Complexes, Author is Zhang, Ping; Morken, James P., which mentions a compound: 147700-62-7, SMILESS is CC(O1)(C)O[C@]2([H])[C@]1([H])C(C3=CC=CC=C3)(C4=CC=CC=C4)OP(C5=CC=CC=C5)OC2(C6=CC=CC=C6)C7=CC=CC=C7, Molecular C37H33O4P, Application of 147700-62-7.
The nickel-catalyzed enantioselective addition of allylboronic acid pinacol ester [allylB(pin)] to α,β,γ,δ-unsaturated aldehydes is described. This reaction results in a remarkable inversion of substrate olefin geometry, providing the Z,E-configured reaction product in good enantioselectivity and olefin stereoselectivity. The reaction appears to proceed by conversion of the dienal to an unsaturated π-allyl complex followed by reductive elimination. Enantioselectivities range from 73-94% ee for a range of δ-substituted dienals when a chiral ligand is employed.
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Reference:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem