Electric Literature of 1532-97-4, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1532-97-4, Name is 4-Bromoisoquinoline, molecular formula is C9H6BrN. In a Article£¬once mentioned of 1532-97-4
Reissert-type acylation with acylzirconocene chloride complexes
In the presence of ClCO2Et, the use of CuI in MeNO2 efficiently catalyzed the Reissert-type acylation of isoquinoline derivatives with acylzirconocene chlorides. In the reaction of quinolines with acylzirconocene chlorides, the choice of catalyst and solvent was crucial to the regioselective formation of adducts. The cationic RhI-catalyzed reaction in MeNO2 preferentially afforded 1,2 adducts. On the other hand, the CuI-catalyzed reaction in CH2Cl2 preferentially afforded 1,4 adducts. In the presence of ClCO2Et, the use of CuI in MeNO2 efficiently catalyzed the Reissert-type acylation of isoquinoline derivatives with acylzirconocene chlorides. In the reaction of quinolines with acylzirconocene chlorides, the catalyst and solvent were crucial to the regioselectivity. The RhI-catalyzed reaction in MeNO 2 preferentially afforded 1,2 adducts, while the 1,4 adducts were obtained with CuI in CH2Cl2. Copyright
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Reference£º
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem