Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 3,5-Di(pyridin-2-yl)-4H-1,2,4-triazol-4-amine, is researched, Molecular C12H10N6, CAS is 1671-88-1, about A 2D CdII coordination polymer constructed from 4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole and tetrabromoterephthalic acid: synthesis, crystal structure and properties.Quality Control of 3,5-Di(pyridin-2-yl)-4H-1,2,4-triazol-4-amine.
Hydrothermal reaction of Cd(OAc)2, 4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole (2-bpt) and tetrabromoterephthalic acid (H2tbta) yields a novel layered network {[Cd(2-bpt)(tbta)](H2O)3}n (1), which was structurally determined by single-crystal x-ray diffraction. 1 Crystallizes in triclinic, space group P1 with a 9.384(3), b 10.652(3), c 14.096(4) Å, α 78.616(4), β 87.101(5), γ 86.555(5)°, Z = 2, Mr = 884.43, dc = 2.132 g/cm3, F(000) = 844, μ = 6.644 mm-1, R = 0.0461 and Rw = 0.1173. The adjacent CdII centers are connected via two 2-bpt mols. to form a 6-membered bimetallic ring, and such rings are further bridged via tbta2- ligands to afford an infinite 2-dimensional coordination framework. Besides, these adjacent layers are extended to the resultant 3-dimensional supramol. network via H-bonding interactions. The thermal stability and fluorescent properties of 1 also were investigated.
This compound(3,5-Di(pyridin-2-yl)-4H-1,2,4-triazol-4-amine)Quality Control of 3,5-Di(pyridin-2-yl)-4H-1,2,4-triazol-4-amine was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem