Yang, Xinyue published the artcileA Mild Method for Access to α-Substituted Dithiomalonates through C-Thiocarbonylation of Thioester: Synthesis of Mesoionic Insecticides, Recommanded Product: 4-Methoxyphenylacetic acid, the main research area is alpha substituted dithiomalonate preparation; thioester imidazole carbothioate thiocarbonylation.
An efficient method for targeting a variety of sym. and asym. αsubstituted dithiomalonates (DTMs) RSC(O)C(R1R2)C(O)SEt [R = Et, i-Pr, t-Bu, Bn, 4-MeC6H4; R1 = H, Me, Ph; R2 = Et, Ph, 4-FC6H4, etc.] was described, utilizing 1H-imidazole-1-carbothioates as reactive acylating agents and MgBr2·OEt2/DBU or LiHMDS for soft or hard enolization conditions of thioesters, resp. The utility of this methodol. was demonstrated through the synthesis of the pyridopyrimidine mesoionic insecticides: triflumezopyrim and dicloromezotiaz.
Advanced Synthesis & Catalysis published new progress about Enolization. 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Recommanded Product: 4-Methoxyphenylacetic acid.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem