Habert, Loic published the artcilePhotoinduced Aerobic Iodoarene-Catalyzed Spirocyclization of N-Oxy-amides to N-Fused Spirolactams, Computed Properties of 104-01-8, the main research area is oxyamide fused spirolactam preparation photoinduced aerobic iodoarene catalyst spirocyclization; aerobic photoredox reaction; dual organocatalysis; hypervalent iodine; pyrylium.
Iodoarene catalysis is a powerful methodol. that usually requires an excess of oxidant, or of redox mediator if the terminal oxidant is dioxygen, to generate the key hypervalent iodine intermediate to proceed efficiently. The authors report that, using the spiro-cyclization of amides as a benchmark reaction, aerobic iodoarene catalysis can be enabled by relying on a pyrylium photocatalyst under blue light irradiation This unprecedented dual organocatalytic system allows the use of low catalytic loading of both catalysts under very mild operating conditions.
Angewandte Chemie, International Edition published new progress about Spiro lactams Role: SPN (Synthetic Preparation), PREP (Preparation) (N-Fused). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Computed Properties of 104-01-8.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem