Su, Wei published the artcileStereoselective Dehydroxyboration of Allylic Alcohols to Access (E)-Allylboronates by a Combination of C-OH Cleavage and Boron Transfer under Iron Catalysis, Name: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, the main research area is iron catalyzed stereoselective dehydroxyboration allylic alc; allyl boronate preparation transformation; carbon hydroxide bond cleavage boron transfer.
Iron-catalyzed direct SN2′ dehydroxyboration of allylic alcs. has been developed to access (E)-stereoselective allylboronates. Allylic alcs. with diverse structures and functional groups, especially derived from natural products, underwent smooth transformation. The six-membered ring transition state formed by allylic alcs. and iron-boron intermediate was indicated to be the key component involved in transfer of the boron group, activation of the C-OH bond, and control of the stereoselectivity.
Organic Letters published new progress about Bond cleavage. 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Name: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem