van Gemmeren, Manuel published the artcileSwitchable Site-Selective Catalytic Carboxylation of Allylic Alcohols with CO2, Safety of 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, the main research area is carbon dioxide allylic alc carboxylation; allylic carboxylic acid regioselective preparation nickel catalyst reaction mechanism; carbon dioxide; cross-coupling; nickel; regioselectivity; synthetic methods.
A switchable site-selective catalytic carboxylation of allylic alcs. has been developed in which CO2 is used with dual roles, both facilitating C-OH cleavage and as a C1 source. This protocol is characterized by its mild reaction conditions, absence of stoichiometric amounts of organometallic reagents, broad scope, and exquisite regiodivergency which can be modulated by the type of ligand employed.
Angewandte Chemie, International Edition published new progress about Carboxylation. 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Safety of 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem