Kim, Myeong Jin published the artcileOxoammonium salt-mediated oxidative nitriles synthesis from aldehydes with ammonium acetate, Category: isoquinoline, the main research area is nitrile preparation; aldehyde ammonium acetate oxoammonium salt oxidation.
An efficient and scalable route for the synthesis of nitriles I [R = n-heptyl, cyclohexyl, 4-MeOC6H4, 2-thienyl, etc.] was developed by oxoammonium salt (4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate) mediated oxidative conversion of aldehydes with ammonium acetate (NH4OAc). A variety of aliphatic aldehydes as well as benzaldehydes were converted into the corresponding nitriles in high yields. The nitroxyl radical which was the reduced species of the used oxoammonium salt was recovered by simple acid-base extraction for the recycling.
Tetrahedron Letters published new progress about Nitriles Role: SPN (Synthetic Preparation), PREP (Preparation). 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Category: isoquinoline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem