Virumbrales, Cintia published the artcileGold(I)-catalyzed nucleophilic cyclization of β-monosubstituted o-(alkynyl)styrenes: A combined experimental and computational study, Quality Control of 151-10-0, the main research area is alkynyl styrene nucleophile gold catalyst diastereoselective regioselective nucleophilic cyclization; alkoxymethyl indene preparation; hydroxymethyl indene preparation; diphenylmethyl indene preparation.
The stereospecific gold(I)-catalyzed nucleophilic cyclization of β-monosubstituted o-(alkynyl)styrenes to produce C-1 functionalized 1H-indenes, including challenging substrates and nucleophiles such as β-(cyclo)alkyl-substituted o-(alkynyl)styrenes and a variety of alcs. as well as selected electron-rich aromatics, is reported. DFT calculations support the stereochem. outcome of the process that involves the formation of a key cyclopropyl gold carbene intermediate through a regiospecific 5-endo cyclization.
Organic & Biomolecular Chemistry published new progress about Alkenynes Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Quality Control of 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem