Li, Ziyong published the artcileConstruction of C-C Axial Chirality via Asymmetric Carbene Insertion into Arene C-H Bonds, SDS of cas: 151-10-0, the main research area is biaryl atropisomer preparation stereoselective; diazonaphthoquinone aniline arene chiral transfer carbene insertion; C-H insertion; asymmetric catalysis; atropisomer; axial chirality; carbene.
By using diazonaphthoquinones and anilines as key reagents and through a point-to-axis chiral transfer strategy, the atroposelective synthesis via asym. C(sp2)-H bond insertion reaction of arenes has been realized under rhodium catalysis, providing the resulting biaryl atropisomers in moderate to excellent yields with good enantiomeric ratios (up to 99:1). Further elaboration indicates this type of axially biaryl scaffold may have promising potentials in developing novel chiral ligands.
Angewandte Chemie, International Edition published new progress about Atropisomers. 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, SDS of cas: 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem