Liu, Yuxia published the artcileHighly Efficient Binuclear Copper-catalyzed Oxidation of N,N-Dimethylanilines with O2, Application In Synthesis of 5961-59-1, the main research area is phenylformamide methyl aniline green preparation; dimethylaniline oxidation binuclear copper catalyst.
A binuclear copper-salicylate complex, [Cu(Sal)2(NCMe)]2 (Sal=salicylate), was found to be an active catalyst for the oxidation of N,N-dimethylanilines by O2, affording the corresponding N-methyl-N-phenylformamides RC6H4N(Me)CHO [R = 4-Br, 3,4-di-F, 3-Cl-4-Me, etc.] as major products and N-methyl-phenylamines RC6H4NHMe as minor products. The reactions were carried out with a O2 balloon and the S/C (substrate/catalyst ratio) of the model reaction could be up to 1×105 providing a practical and highly efficient catalytic protocol for accessing N-methyl-N-phenylformamides.
ChemCatChem published new progress about Formamides Role: SPN (Synthetic Preparation), PREP (Preparation) (Ph). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Application In Synthesis of 5961-59-1.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem