Wei, Duo published the artcileRhenium-Catalyzed Reduction of Carboxylic Acids with Hydrosilanes, Computed Properties of 104-01-8, the main research area is rhenium catalyzed photochem reduction carboxylic acid hydrosilane; disilylacetal preparation; aldehyde preparation.
Re2(CO)10 efficiently catalyzes the direct reduction of various carboxylic acids under mild conditions (rt, irradiation 350 or 395 nm). While aliphatic carboxylic acids were readily converted to the corresponding disilylacetals with low catalyst loading (0.5 mol %) in the presence of Et3SiH (2.2 equiv), aromatic analogs required more drastic conditions (Re2(CO)10 5 mol %, Ph2MeSiH 4.0 equiv) to afford the corresponding aldehydes after acid treatment.
Organic Letters published new progress about Acetals Role: SPN (Synthetic Preparation), PREP (Preparation) (disilylacetals). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Computed Properties of 104-01-8.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem