Heberle, Martin published the artcileBispalladacycle Catalyzed Nucleophilic Enantioselective Allylation of Aldehydes by Allylstannanes, Product Details of C9H10O3, the main research area is aldehyde allylstannane palladacycle catalyst nucleophilic enantioselective allylation; homoallylic alc preparation.
The first palladium catalysts capable of controlling asym. nucleophilic allylations of aldehydes with allyltributyltin was reported. TONs up to 620 were achieved, which is significantly higher than for any other reported catalyst. The method also tolerated electronically and sterically unfavorable substrates. It was showed that transmetallation occurred, favoring an η1-allyl coordination mode with the bispalladacycles. In contrast, for the corresponding monopalladacycle an unproductive η3 coordination was dominant.
ChemCatChem published new progress about Alcohols, homoallylic Role: SPN (Synthetic Preparation), PREP (Preparation). 86-51-1 belongs to class isoquinoline, name is 2,3-Dimethoxybenzaldehyde, and the molecular formula is C9H10O3, Product Details of C9H10O3.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem