Paul, Dipankar published the artcileA facile iron-catalyzed dual C-C bond cleavage: an approach towards triarylmethanes, HPLC of Formula: 151-10-0, the main research area is triarylmethane preparation; benzyl substituted diketone nucleophile dual bond cleavage iron catalyst.
A facile iron-catalyzed dual C-C bond cleaving reaction involving 1,3-dicarbonyl units along with electron-rich and sterically bulky arenes as efficient carbon-based leaving groups was developed. The scope of the dual C-C bond breaking reaction was studied in detail using a range of nucleophiles to synthesize sym. triarylmethanes in good to excellent yields. The intermediate of the reaction was isolated which was formed via the initial Csp3-Csp3 bond cleavage and subsequently converted the intermediate to the final product via the Csp3-Csp2 bond cleavage. A notable difference in the leaving aptitudes of the two carbon-based leaving groups perceived during the study enabled us to develop an application of the dual C-C bond breaking reaction for the synthesis of unsym. triarylmethanes in a stepwise manner. To improve the synthetic utility, a one-pot procedure to generate unsym. triarylmethanes via sequential C-C bond breaking reactions were also fashioned . In addition to studying a novel dual C-C bond breaking reaction and providing a hint to the mechanistic pathway, the application molded from the study for the synthesis of sym. and especially unsym. triarylmethanes may render value to the present work.
New Journal of Chemistry published new progress about 1,3-Dicarbonyl compounds Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, HPLC of Formula: 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem