Jones, Roderick C. published the artcileControlling reactivity in the Fujiwara-Moritani reaction: Examining solvent effects and the addition of 1,3-dicarbonyl ligands on the oxidative coupling of electron rich arenes and acrylates, Computed Properties of 151-10-0, the main research area is Fujiwara Moritani dicarbonyl ligand oxidative coupling arene acrylate solvent.
A palladium-catalyzed direct alkenylation of electron rich arenes in the presence of K2S2O8 with an acetic acid/1,4-dioxane solvent combination was developed. The 1,4-dioxane co-solvent dramatically influences the rate of reaction, giving selectively disubstituted alkenes, while the addition of acetylacetone ligands increases site selectivity for the alkenylation of monofunctionalized arenes. The participation of these carbonyl ligands was confirmed by ESI-MS studies, with some key in situ intermediates in the catalytic cycle identified. A variety of electron rich arenes and olefinic substrates can be used in the direct oxidative coupling to give disubstituted alkenes in moderate to good yields.
Tetrahedron Letters published new progress about 1,3-Dicarbonyl compounds Role: CAT (Catalyst Use), USES (Uses). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Computed Properties of 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem