Ribeiro Gouveia, Liana published the artcileWell-Defined ENENES Re and Mn Complexes and Their Application in Catalysis: The Role of Potassium tert-Butoxide, Application In Synthesis of 86-51-1, the main research area is rhenium complex bidentate thienyldiamine ligand preparation catalyst aldehyde hydrogenation; manganese complex bidentate thienyldiamine ligand preparation catalyst aldehyde hydrogenation; crystal structure rhenium carbonyl complex bidentate thienyldiamine ligand; mol structure rhenium carbonyl complex bidentate thienyldiamine ligand.
A new family of air-stable Re and Mn complexes bearing bidentate NNS (ENENES) ligands E(CH2)2NH(CH)2SR (E = -NC4H8O or -NC5H10, R = Ph or thiophenyl) is introduced. All Re and Mn complexes were catalysts for the hydrogenation of aldehydes. The Mn catalysts were active at milder conditions. A Re-hydride complex, featuring cis Re-H and N-H moieties, was isolated to provide an insight into the mechanism for this reaction. DFT (B3PW91-D3) and probably there are two pathways for this system, with and without the presence of the base (t-BuOK). The pathway that included t-BuOK was lower in energy, providing a greater driving force for the overall reaction.
Organometallics published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 86-51-1 belongs to class isoquinoline, name is 2,3-Dimethoxybenzaldehyde, and the molecular formula is C9H10O3, Application In Synthesis of 86-51-1.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem