Qian, Bing-Feng published the artcileNew (μ-oxo)bis(μ-carboxylato)diruthenium(III) complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononane ligands, Related Products of isoquinoline, the main research area is dinuclear ruthenium trimethyltriazacyclononane benzoato phenylacetato complex catalyst preparation electrochem; crystal structure dinuclear ruthenium trimethyltriazacyclononane benzoato phenylacetato complex.
Treatment of [(Me3tacn)RuCl3·H2O] (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) with substituted benzoic acid or phenylacetic acid, in water in the presence of potassium hexafluorophosphate gave cationic dinuclear Ru(III)-Ru(III) (μ-oxo)bis(μ-carboxylato) complexes [(Me3tacn)2Ru2(μ-O)(μ-OOCR)2](PF6)2 (R = Ph, 1; -py, 2; -C6H4-2-Cl, 3; -C6H3-2,4-Cl2, 4; -CH2C6H4-2-CH3, 5; -CH2C6H4-4-CH3, 6; -CH2C6H4-4-OCH3, 7; -CH2C6H4-4-Cl, 8). All complexes are well characterized by IR, UV/visible and mass spectroscopies, and their electrochem. properties were also investigated. The mol. structures of 1, 2·2C3H6O, 5·2C3H6O, 7 and 8 were also established by single-crystal x-ray diffraction. The photocatalytic properties for H2 evolution by water splitting of complexes 1, 2, 3, 5, and 7 were also investigated.
Inorganica Chimica Acta published new progress about Benzoic acids Role: RCT (Reactant), RACT (Reactant or Reagent). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Related Products of isoquinoline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem