Schuhmacher, Anne published the artcileCatalytic Synthesis of Potassium Acyltrifluoroborates (KATs) from Boronic Acids and the Thioimidate KAT Transfer Reagent, Product Details of C2H6N2O, the main research area is potassium acyltrifluoroborate preparation; boronic acid thioimidate transfer reagent cross coupling palladium catalyst; acylboron compounds; boronic acids; cross-coupling; synthetic methods; zwitterions.
We report the synthesis of potassium acyltrifluoroborates (KATs) by a palladium-catalyzed cross-coupling of boronic acids and the thioimidate KAT transfer reagent. The combination of widely available aryl- and vinylboronic acids with com. available thioimidate using catalytic PdII and a CuII additive enables the preparation of KATs in high yields and with good functional group tolerance. This formal insertion of CO into organoboronic acids can also be applied to boronic acid pinacol esters and potassium organotrifluoroborates using a slightly modified procedure. The cross-coupling can be telescoped into the one-pot synthesis of amides and α-aminotrifluoroborates by exploiting the unique chem. of KATs and their trifluoroborate iminium (TIM) derivatives
Angewandte Chemie, International Edition published new progress about Boronic acids Role: RCT (Reactant), RACT (Reactant or Reagent). 598-50-5 belongs to class isoquinoline, name is 1-Methylurea, and the molecular formula is C2H6N2O, Product Details of C2H6N2O.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem