Chen, Yu published the artcileTotal Synthesis of Denigrin E and Its Oxidative Conversion into Co-occurring Metabolite Denigrin D, COA of Formula: C9H10O3, the main research area is denigrin E total synthesis oxidative rearrangement denigrin D.
An unambiguous, six-step total synthesis of denigrin E (5) from anisaldehyde 22 has been achieved, confirming the structure of this marine natural product. On treatment with t-BuOOH/Mo(CO)6, compound 5 undergoes a unique and possibly biogenetically relevant oxidative rearrangement to generate the co-occurring metabolite denigrin D (4), which is obtained in 61% yield.
Organic Letters published new progress about Molecular structure, natural product (structure confirmation). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, COA of Formula: C9H10O3.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem