Chalk, Alan J. published the artcilePalladium-catalyzed vinyl substitution reactions. II. Synthesis of aryl substituted allylic alcohols, aldehydes, and ketones from aryl halides and unsaturated alcohols, Recommanded Product: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, the main research area is allylic alc aryl halide; ketone aralkyl; aldehyde aralkyl.
Addnl. data considered in abstracting and indexing are available from a source cited in the original document. A variety of substituted bromo- and iodobenzenes reacted with CH2:CMeCH2OH, CH2:CHCHMeOH, and CH2:CHCMe2OH in the presence of PdCl2 or Pd(OAc)2 and PPh3 to give, resp., Ph substituted derivatives of PhCH2 CHMeCHO, Ph(CH2)2COMe, and PhCH:CHCMe2OH. With some nonallylic unsaturated alcs., carbonyl compounds were formed via double bond migration. Formation of the intermediate aryl-substituted unsaturated alcs. was minimal unless a quaternary carbon separated the double bond from the alc. function.
Journal of Organic Chemistry published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Recommanded Product: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem