Zhang, Lei published the artcileRhenium-catalyzed alkylarylation of alkenes with PhI(O2CR)2via decarboxylation to access indolinones and dihydroquinolinones, Product Details of C8H11NO, the main research area is indolinone preparation regioselective; alkene hypervalent iodine compound cyclization rhenium catalyst; dihydroquinolinone preparation regioselective diastereoselective; cinnamamide hypervalent iodine compound cyclization rhenium catalyst.
Rhenium-catalyzed alkylarylation of alkenes RN(R1)C(O)C(=CH2)R2 (R = C6H5, 4-FC6H4, 2-CH3C6H4, etc.; R1 = CH3, CH2CH3, CH(CH3)2, C(O)CH3; R2 = Me, Ph) and 4-R3C6H4N(Me)C(O)CH=CHAr (R3 = Me, F, OMe, etc.; Ar = C6H5, 4-ClC6H4) with hypervalent iodine(III) reagents (HIRs) PhI(O2CR4)2 (R4 = Me, i-Pr, cyclopropyl, etc.) via decarboxylation to access various 3,3-disubstituted indolinones I (R5 = 5-F, 7-Me, 5-CN, etc.) and trans-3,4-dihydroquinolinones trans-II (R6 = Me, F, CF3, etc.) is described. These transformations feature wide substrate scopes, good functional-group tolerance, and divergent regioselectivity. Mechanistic studies revealed a cascade sequence of decarboxylation/intermol. radical alkylation/intramol. radical arylation/oxidative re-aromatization.
Organic Chemistry Frontiers published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Product Details of C8H11NO.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem