Wu, Fan published the artcileRegioselective Formal [3+2] Cycloadditions of Urea Substrates with Activated and Unactivated Olefins for Intermolecular Olefin Aminooxygenation, HPLC of Formula: 598-50-5, the main research area is urea olefin iodide catalyst regioselective diastereoselective cycloaddition; aminooxazoline stereoselective preparation; alkenes; aminooxygenation; cycloaddition; homogeneous catalysis; oxazoline.
A new class of intermol. olefin aminooxygenation reaction is described. This reaction utilizes the classic halonium intermediate as a regio- and stereochem. template to accomplish the selective oxyamination of both activated and unactivated alkenes. Notably, urea chem. feedstock can be directly introduced as the N and O source and a simple iodide salt can be utilized as the catalyst. This formal [3+2] cycloaddition process provides a highly modular entry to a range of useful heterocyclic products, e.g., I, with excellent selectivity and functional-group tolerance.
Angewandte Chemie, International Edition published new progress about [3+2] Cycloaddition reaction catalysts. 598-50-5 belongs to class isoquinoline, name is 1-Methylurea, and the molecular formula is C2H6N2O, HPLC of Formula: 598-50-5.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem