Wang, Xinchao published the artcileNative carboxyl group-assisted C-H acetoxylation of hydrocinnamic and phenylacetic acids, COA of Formula: C9H10O3, the main research area is acid preparation; hydrocinnamic acid iodosobenzene diacetate acetoxylation palladium catalyst; phenylacetic acid iodosobenzene diacetate acetoxylation palladium catalyst.
A method of native carboxyl-assisted, Pd(II)-catalyzed ortho-C-H acetoxylation of both hydrocinnamic and phenylacetic acids 2-R-3-R1-4-R2C6H2CH(R3)CH2C(O)OH (R = H, Me, Cl, OCF3, etc.; R1 = Me, Br, CF3, etc.; R2 = Me, F, COOMe, etc.; R3 = H, Me, Et)/2-R4-3-R5-4-R6-5-R7C6HC(R8)(R9)C(O)OH (R4 = H, Me, I, etc.; R5 = H, OMe, CF3, etc.; R6 = F, OMe, COOMe, etc.; R7 = R8 = R8 = H, Me) that can be found in many biol. active mols. as the key moieties was reported. Based on the broad scope and the application potential showcased with drug mols., such as (ibuprofen, ketoprofen, and flurbiprofen) it is anticipated that this C-H acetoxylation reaction will find attractive applicability in future synthetic endeavors.
Chemical Communications (Cambridge, United Kingdom) published new progress about Acetoxylation (carbon-hydrogen). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, COA of Formula: C9H10O3.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem