Aegurla, Balakrishna published the artcileDehydrative C- and S-Alkylation: Access to Highly Substituted 1-Sulfonylpropanes, SDS of cas: 151-10-0, the main research area is aryl sulfonylpropane preparation; hydroxysulfone arene thiophenol dehydrative alkylation.
A dehydrative C- and S-alkylation procedure by nucleophilic substitution of γ-hydroxysulfones with arenes and thiophenols is reported. This study represents an elegant and ecol. concept to construct C-C and C-S bonds leading to unsym. 1,1- and 3,3-branched propanes. The γ-hydroxysulfones underwent BF3.OEt2-mediated dehydrative arylation and thiolation at room temperature and elimination at 40°. The nucleophile attack occurred on the less hindered side of a planar benzylic carbocation to furnish the title compounds with good diastereoselectivity.
Asian Journal of Organic Chemistry published new progress about Alkylation, stereoselective. 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, SDS of cas: 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem